1) I'd prefer someone else to confirm my answers but I think the chances of one specific edge being paired with any 3rd layer corner in a specific orientation is 1/6 (1/3 chance of being oriented and 1/2 chance of being from the last layer). That means that the odds of at least one out of two specific edges being like that are 11/36, and for at least one out of 3 is 91/216 and for at least one of four specific edges, its 671/1296 or 51.77%.
2) Not sure I understand. Can you give an example?
3) Not sure how to work this out, because the state after 1 move is not completely independent of the state before that move. I think that the answer depends on how inefficient your solution is. The more moves you take, the more likely it is to happen, I'm sure.
4) Yes 1/81 is correct.
5) Yes, if the corner you insert is oriented then the chance of the rest also being oriented is 1/27. And if you don't influence permutation of the other corners during CLS, then yes, theres a 1/72 chance of a PLL skip. That means there's a 49/972 (about 5%) chance of skipping at least one of OLL or PLL and 1/1944 chance of skipping both. Same as nomal OLL+PLL for ZZ.