I think God's Number for the 4x4x4 is 32.
I extended the recursive accumulator for unique 4x4x4 positions out this far. I noticed at depth 31, you get
470,703,927,480,007,324,417,289,104,727,084,394,384,064,512
...and at depth 32, you get
12,875,779,855,238,747,700,213,127,810,947,408,348,230,811,648.
If there are 7,401,196,841,564,901,869,874,093,974,498,574,336,000,000,000 unique arrangements, then the total arrangements possible at depth 31 is too small to represent this number, and the depth 32 count is finally greater than it. I'm not sure at what point the cumulative total exceeds it, but to err on the side of caution, we can set 32 as the safe upper bound
I have the numbers for depths 1 to 16 listed here:
http://lightningcloudcomputing.com/OO_4x4x4/info_05.shtml
I'll fill the rest of them in later.