That is an interesting analysis, and very ingenious way of testing the scrambles. I haven't read through all the replies yet, but I am assuming the experimental St Dev column has an error, since you only performed the test on 10^6 scrambles. Do you know what this error would be?
I'd also be curious to see this done for big cube scrambles using a different scramble algorithm: misalign each break on an axis, switch to another, and repeat. Normalizing these scrambles by the number of HTM moves performed, it would be nice to see how much more (or less) efficiently this method scrambles than the WCA scrambler for big cubes. It would also be nice to compare the WCA algorithm to one that randomly misaligns breaks (without backtracking) (note that the WCA scrambler doesn't actually do this - it has a bias in that it tends to perform turns on the same axis more often than the aforementioned alg would).






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